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Beilstein J. Org. Chem. 2023, 19, 1604–1614, doi:10.3762/bjoc.19.117
Graphical Abstract
Figure 1: Structures of compounds 1–7.
Figure 2: Key HMBC (red arrows), H2BC (black bold lines), and COSY (blue bold lines) correlations in 1 and 2.
Figure 3: a) Simplified model structures 1′ and 2′ for GIAO and TD-DFT calculations. b) Comparison of experim...
Figure 4: Key HMBC (red arrows), H2BC (black bold lines), and COSY (blue bold lines) correlations in compound...
Figure 5: Comparison of experimental (black solid line) and calculated (red dashed line) ECD spectra of 3.
Figure 6: Anti-inflammatory effects of isolated sulfur-containing compounds. mRNA levels of a) IL-1β, b) IL-6...
Beilstein J. Org. Chem. 2020, 16, 2100–2107, doi:10.3762/bjoc.16.177
Figure 1: Structures of compounds 1–4.
Figure 2: Key HMBC (green arrows) and COSY (bold) correlations in 1 and 2.
Scheme 1: (A) Synthesis of MTPA diesters 1a and 1b. (B) Δδ Values for the (S)- and (R)-MTPA esters of 1.
Figure 3: Simplified model structures for calculations of the ECD spectra of 1.
Figure 4: Comparison of the experimental ECD spectra (black solid line) of 1 (A) and 2 (B) with the Boltzmann...
Beilstein J. Org. Chem. 2020, 16, 290–296, doi:10.3762/bjoc.16.28
Figure 1: Structures of compounds 1–6.
Figure 2: Key HMBC (blue arrows) and COSY (bold bonds) correlations in 1 and 2.
Figure 3: a) ORTEP drawing of 1, with thermal ellipsoids indicating 50% probability. The atoms of the minor d...
Figure 4: a) ORTEP drawing of 3, with thermal ellipsoids indicating 50% probability. b) Electronic circular d...
Figure 5: a) ORTEP drawing of 5, with thermal ellipsoids indicating 50% probability. b) Electronic circular d...